論文 2023

▼【分野・専攻だより】SDGsを達成せよ！元素戦略を推進するキラル鉄(Ⅲ)光レドックス触媒の開発

石原一彰、大村修平

PRESS e, 2023, No. 49, page 9 (2023年12月発行）

https://cd.engg.nagoya-u.ac.jp/press_e/major/m49_01.html

▼Tandem Isomerization/α,β-Site-Selective and Enantioselective Addition Reactions of N-(3-Butynoyl)-3,5-dimethylpyrazole Induced by Chiral π–Cu(II) Catalysts

Weiwei Guo, Masahiro Hori, Yoshihiro Ogura, Kazuki Nishimura, Kosuke Oki, Tomoyuki Ikai, Eiji Yashima, Kazuaki Ishihara*

J. Am. Chem. Soc. 2023, 145(49), 27080–27088. OPEN ACCESS

Publication Date: November 30, 2023

https://doi.org/10.1021/jacs.3c10820

名古屋大学プレスリリース（2023年12月5日）

最小人工金属酵素：π－銅(Ⅱ)錯体触媒が切り拓く新たな有機合成法～単離困難なアレンアミドの実用的不斉付加反応に成功～

日本の研究.com（2023年12月6日）

最小人工金属酵素：π－銅(Ⅱ)錯体触媒が切り拓く新たな有機合成法～単離困難なアレンアミドの実用的不斉付加反応に成功～

▼日本の研究.com「基質包接型キラル大環状ジリチウム(I)塩触媒の開発　〜高付加価値化合物の迅速合成で医薬品探索研究を切り拓く〜」（2023年11月9日）

▼名古屋大学プレスリリース「基質包接型キラル大環状ジリチウム(I)塩触媒の開発　〜高付加価値化合物の迅速合成で医薬品探索研究を切り拓く〜」（2023年11月8日）

▼EurekAlert "English press release about "New catalytic technique creates key component of incontinence drug in less time" (11-Jan-2024)

▼AlphaGalileo "English press release about "New catalytic technique creates key component of incontinence drug in less time" (12-Jan-2024, Top 1 Story)

▼NU Research Information "English press release about "New catalytic technique creates key component of incontinence drug in less time" (15-Jan-2024)

▼[Supplementary Cover Art] Chiral Macrocyclic Catalysts for the Enantioselective Addition of Lithium Acetylides to Ketones

Kenji Yamashita, Yuji Tabata, Katsuya Yamakawa, Takuya Mochizuki, Kei Matsui, Manabu Hatano,* Kazuaki Ishihara*

J. Am. Chem. Soc. 2023, 145(48), 26238–26248.

https://pubs.acs.org/doi/10.1021/jacs.3c08905

An enantioselective addition of lithium acetylides to ketones catalyzed by macrocyclic lithium binaphtholates has been developed. The macrocyclic structure prevents aggregation, affording a monomeric and highly active catalyst that can furnish enantioenriched tertiary alcohols within 5–30 min. Moreover, the confined cavity and lipophilicity of the macrocycle confer substrate specificity.

▼Chiral Macrocyclic Catalysts for the Enantioselective Addition of Lithium Acetylides to Ketones

Kenji Yamashita, Yuji Tabata, Katsuya Yamakawa, Takuya Mochizuki, Kei Matsui, Manabu Hatano,* Kazuaki Ishihara*

J. Am. Chem. Soc. 2023, 145(48), 26238–26248.

Published: November 4, 2023

https://pubs.acs.org/doi/10.1021/jacs.3c08905

▼[Commentary] Recent Progress of Iodine Catalysis Directed toward Environmentally more Benign and Sustainable Chemistry

Kazuaki Ishihara

Adv. Synth. Catal. 2023, 365(16), 2652–2652. Free Access

First published: 23 August 2023

▼Special Issue: Iodine in Catalysis and Organic Synthesis

Issue Editor: Kazuaki Ishihara

Adv. Synth. Catal. 2023, 365(16), 2651-2762.

Published: August 15, 2023

https://onlinelibrary.wiley.com/toc/16154169/2023/365/16

▼【最新のトピックス】キラルカウンターアニオンストラテジーの今　ー　不斉ラジカルカチオン反応への挑戦

大村修平、石原一彰

化学 2023, 78(9), 68–69.

▼縮合剤を用いない触媒的ペプチド合成

石原一彰細胞, 2023, 55(9), 682–684.
ニューサイエンス社

▼オンリーワンといえるようなテーラーメイド触媒の開発を目指して　ーレディメイドからテーラーメイドへのパラダイムシフト

石原一彰
ドラマティック有機合成化学　感動の瞬間100 pp. 60–61.
化学同人, 2023年7月30日発行, ISBN 978-4-7598-2336-3

▼Hypoiodite-Catalyzed Oxidative α-C–N Coupling of Ketones with Imides and Azoles

Mayuko Tsukahara, Muhammet Uyanik,* Kazuaki Ishihara*
Adv. Syth. Catal. 2023, 365(16), 2724–2729. Very Important Publication
First published: 17 July 2023

https://doi.org/10.1002/adsc.202300716

▼Highly Enantioselective Radical Cation [2 + 2] and [4 + 2] Cycloadditions by Chiral Iron(III) Photoredox Catalysis

Shuhei Ohmura, Kei Katagiri, Haruna Kato, Takahiro Horibe, Sho Miyakawa, Jun-ya Hasegawa, and Kazuaki Ishihara*

J. Am. Chem. Soc. 2023, 145(28), 15054–15060.

Publication Date: July 5, 2023

https://pubs.acs.org/doi/10.1021/jacs.3c04010

名古屋大学プレスリリース（2023年7月6日）

「キラル鉄(Ⅲ)光レドックス触媒の開発～SDGsと元素戦略に基づく医薬品探索研究を推進～」

日本の研究.com（2023年7月7日）

「キラル鉄(Ⅲ)光レドックス触媒の開発～SDGsと元素戦略に基づく医薬品探索研究を推進～」

Chem-Station (ケムステ)（2023年8月16日）

「難攻不落の不斉ラジカルカチオン反応への挑戦」

▼A Lewis base–silyl Lewis acid cooperative catalyst for the iodochlorination of tetrasubsttuted alkenes

Keigo Nagami, Shuhei Ohmura,* and Kazuaki Ishihara*

Asian J. Org. Chem. 2023, 12, e20230228 (4 pages). (Special Selection: Keiji Maruoka's 70th Birthday)

DOI: 10.1002/ajoc.202300228

Publication Date: May 25, 2023.

▼触媒的エナンチオ選択的α-ハロゲン化反応に潜むハロゲン結合の影響

石原一彰

有機合成化学協会雑 2023, 81(5), 474–482.

発行日：2023/05/01, 公開日：2023/5/10

DOI: 10.5059/yukigoseikyokaishi.81.474

▼1,3-Migrative ring expansion of spiroindolenines to azepino[3,4-b]indoles

Hiroki Tanaka, Toshihiro Yasui, Muhammet Uyanik,* and Kazuaki Ishihara*

Org. Lett. 2023, 25(14), 2377–2381.

DOI: 10.1021/acs.orglett.3c00207

Publication Date: February 27, 2023. Front Cover

▼Catalyst-Substrate Helical Character Matching Determines the Enantioselectivity in the Ishihara-Type Iodoarenes Catalyzed Asymmetric Kita-Dearomative Spirolactonization

Authors: Hanliang Zheng, Liu Cai, Ming Pan, Muhammet Uyanik, Kazuaki Ishihara, Xiao-Song Xue*

J. Am. Chem. Soc. 2023, 25(14), 7301–7312.

DOI: 10.1021/jacs.2c13295

Publication Date: March 20, 2023

▼Catalytic site-, diastereo-, and enantioselective cascade iodocyclizaton of 2-geranylarenols

Yasutaka Tsuji, Kazumasa Kon, Takahiro Horibe and Kazuaki Ishihara*

Chem. Asian J. 2023, 18(7), e202300019 (Special Collection on Halogen Bonding).

DOI: 10.1002/asia.202300019

First published: 6 Feb., 2023

▼Enantioselective aromatic Claisen rearrangement of allyl 2-naphthyl ethers catalyzed by π–Cu(II) complexes

Lu Yao, Kazuki Takeda, Kaori Ando* and Kazuaki Ishihara*

Chem. Sci. 2023, 14(9), 2441–2446.

DOI: 10.1039/D2SC06771D

First published: 20 Jan., 2023

▼Bulky magnesium(II) and sodium(I) bisphenoxide catalysts for chemoselective transesterification of methyl (meth)acrylates

Xue Zhao, Manussada Ratanask, Kazumasa Kon, Jun-ya Hasegawa* and Kazuaki Ishihara*

Chem. Sci. 2023, 14(3), 566–572.

DOI: 10.1039/D2SC05413B (Publication Date: November 28, 2022)